2-(Ethoxycarbonyl)quinolinium butyltrichlorido(quinoline-2-carboxylato-κ2 N,O)stannate(IV)
نویسندگان
چکیده
In the title compound, (C(12)H(12)NO(2))[Sn(C(4)H(9))(C(10)H(6)NO(2))Cl(3)], the Sn atom is coordinated by one O and one N atom of a quinolinium-2-carboxyl-ate anion, three Cl atoms and one butyl ligand within a distorted octa-hedron. Three C atoms of the butyl ligand are disordered and were refined using a split model; the site occupancies are 0.57 and 0.43. The NH group of the cation is involved in inter-molecular N-H⋯O hydrogen bonding.
منابع مشابه
2-(Methoxycarbonyl)quinolinium tetrachlorido(quinoline-2-carboxylato-κ2 N,O)stannate(IV) methanol solvate
In the title salt, (C(11)H(10)NO(2))[SnCl(4)(C(10)H(6)NO(2))]·CH(3)OH, the Sn atom is chelated by the quinolincarboxyl-ate unit and it exists in a distorted octa-hedral coordination geometry. The cation is linked to the solvent mol-ecule by an N-H⋯O hydrogen bond; the solvent mol-ecule is linked to the anion by an O-H⋯O hydrogen bond.
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متن کامل8-Hydroxy-2-methylquinolinium tetrachlorido(pyridine-2-carboxylato-κ2 N,O)stannate(IV)
In the reaction of pyridine-2-carb-oxy-lic acid and stannic chloride in the presence of 2-methyl-8-hy-droxy-quinoline, the 2-methyl-8-hy-droxy-quinoline is protonated, yielding the title salt, (C(10)H(10)NO)[SnCl(4)(C(6)H(4)NO(2))]. The Sn(IV) atom in the anion is N,O-chelated by a pyridine-2-carboxyl-ate in a cis-SnNOCl(4) octa-hedral geometry. The cation is linked to the anion by an O-H⋯O hyd...
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In the title salt, (C(13)H(14)NO(2))[Sn(C(10)H(6)NO(2))Cl(4)], the Sn(IV) cation is N,O-chelated by the quinolincarboxyl-ate unit and further coordinated by four Cl(-) anions in a distorted octa-hedral geometry. In the crystal, the 2-[(propan-2-yl-oxy)-carbon-yl]quinolin-1-ium cation is linked to the Sn complex anion by an N-H⋯O hydrogen bond.
متن کاملTriethylammonium tetrachlorido(pyridine-2-carboxylato-κ2 N,O)stannate(IV)
The cation and the anion in the title salt, (C(6)H(16)N)[SnCl(4)(C(6)H(4)NO(2))], are linked by an N-H⋯O hydrogen bond. The Sn(IV) atom in the stannate anion is chelated by the pyridine-2-carboxyl-ate group and exists in a cis-SnCl(4)NO octa-hedral geometry. The cation is disordered over two positions in a 0.564 (1):0.436 (1) ratio.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008